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Which of the following might be obtained as one of the products in this reaction? Which of the following might be obtained as one of the products in this reaction?   A)    B)    C)    D)


A)
Which of the following might be obtained as one of the products in this reaction?   A)    B)    C)    D)
B)
Which of the following might be obtained as one of the products in this reaction?   A)    B)    C)    D)
C)
Which of the following might be obtained as one of the products in this reaction?   A)    B)    C)    D)
D)
Which of the following might be obtained as one of the products in this reaction?   A)    B)    C)    D)

E) A) and B)
F) None of the above

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What is the IUPAC name of the molecule shown? What is the IUPAC name of the molecule shown?   A) diethanoic acid B) ethanedioc C) dibutanoic acid D) butanedioic acid E) pentanedioic acid


A) diethanoic acid
B) ethanedioc
C) dibutanoic acid
D) butanedioic acid
E) pentanedioic acid

F) A) and B)
G) A) and E)

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Match the following. -phosphorylation


A) a molecule that contains one phosphate ester linkage and one phosphoric anhydride linkage
B) a molecule that contains one phosphate ester linkage and two phosphoric anhydride linkages
C) a polymer produced by reacting diamines with diacids or diacyl chlorides
D) a functional group formed when two acid molecules give up one water molecule
E) a functional group consisting of an amine group bonded to a carbonyl carbon
F) the type of ester produced when phosphoric acid reacts with two molecules of alcohol
G) a functional group consisting of a carbonyl carbon with a single bond to another oxygen; the remaining bonds are formed with R groups
H) the carbon atom bonded directly to the carbonyl carbon atom
I) the type of ester produced when phosphoric acid reacts with three molecules of alcohol
J) The common name of this compound is acetic acid.
K) the type of ester produced when phosphoric acid reacts with one molecule of alcohol
L) the transfer of a phosphoryl group from one molecule to another
M) The common name of this compound is formic acid.

N) H) and K)
O) I) and M)

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What is the IUPAC name of the compound shown? What is the IUPAC name of the compound shown?   A) 3-hexanoic acid B) 2-ethyl pentanoate C) 2-ethylpentanoic acid D) 3-heptanoic acid E) 4-heptanoic acid


A) 3-hexanoic acid
B) 2-ethyl pentanoate
C) 2-ethylpentanoic acid
D) 3-heptanoic acid
E) 4-heptanoic acid

F) A) and B)
G) C) and D)

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Carboxylic acids generally taste ________.


A) sour
B) sweet
C) bitter
D) salty
E) spicy

F) None of the above
G) A) and B)

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The products of acid hydrolysis of an ester are


A) another ester + water.
B) alcohol + acid.
C) alcohol + water.
D) acid + water.
E) salt + water.

F) A) and D)
G) B) and D)

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An acyl group is a group in which


A) an amine and a carbonyl are bonded to the same carbon atom.
B) a hydroxyl and an alkene are bonded to the same carbon atom.
C) an alpha carbon is bonded to an alkyl group.
D) an alkyl group is bonded to a carbonyl carbon atom.
E) an acidic group is bonded to an aromatic group.

F) All of the above
G) B) and E)

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Which of the compounds shown can form hydrogen bonds with other identical molecules? Explain each case. Which of the compounds shown can form hydrogen bonds with other identical molecules? Explain each case.

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Molecules 2,4,and 5 can form hydrogen bo...

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Which acid would be expected to have the lowest boiling point?


A) acetic,CH3CO2H
B) benzoic,C6H5CO2H
C) formic,HCO2H
D) oxalic, (CO2H) 2
E) stearic,CH3(CH2) 16CO2H

F) A) and E)
G) All of the above

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This compound is This compound is   A) an anhydride only. B) an ester only. C) both an ester and an anhydride. D) neither an ester nor an anhydride. E) phosphoric acid.


A) an anhydride only.
B) an ester only.
C) both an ester and an anhydride.
D) neither an ester nor an anhydride.
E) phosphoric acid.

F) B) and D)
G) A) and E)

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All of the statements about carboxylic acids are true except


A) they undergo substitution reactions involving the -OH group.
B) at low molecular weights they are liquids with sharp stinging odors.
C) they form hydrogen bonds,causing their boiling points to be higher than expected on the basis of molecular weight.
D) they react with bases to form salts which are often more soluble than the original acid.
E) when they behave as acids,the -OH group is lost leaving the CO- ion.

F) D) and E)
G) B) and E)

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The common chemical name of aspirin is


A) acetamide.
B) acetylsalicylic acid.
C) phenylalanyl aspartic acid.
D) acetaminophen.
E) lidocaine.

F) C) and E)
G) D) and E)

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The potassium or sodium salt of a long chain carboxylic acid is called a


A) soap.
B) triglyceride.
C) ester.
D) emollient.
E) none of the above

F) All of the above
G) A) and C)

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Which compound is a carboxylic acid?


A) CH3COO-K+
B) CH3COOH
C) (CH3) 2CHOOCH3
D) (CH3CO) 2O
E) (CH3) 2O

F) B) and C)
G) A) and E)

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The functional groups in the aspirin molecule shown are The functional groups in the aspirin molecule shown are   A) aromatic,carboxylic acid. B) aromatic,ester. C) carboxylic acid,ester. D) aromatic,carboxylic acid,ester. E) amide,aromatic,carboxylic acid.


A) aromatic,carboxylic acid.
B) aromatic,ester.
C) carboxylic acid,ester.
D) aromatic,carboxylic acid,ester.
E) amide,aromatic,carboxylic acid.

F) C) and E)
G) A) and B)

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Match the following. -alpha carbon


A) a molecule that contains one phosphate ester linkage and one phosphoric anhydride linkage
B) a molecule that contains one phosphate ester linkage and two phosphoric anhydride linkages
C) a polymer produced by reacting diamines with diacids or diacyl chlorides
D) a functional group formed when two acid molecules give up one water molecule
E) a functional group consisting of an amine group bonded to a carbonyl carbon
F) the type of ester produced when phosphoric acid reacts with two molecules of alcohol
G) a functional group consisting of a carbonyl carbon with a single bond to another oxygen; the remaining bonds are formed with R groups
H) the carbon atom bonded directly to the carbonyl carbon atom
I) the type of ester produced when phosphoric acid reacts with three molecules of alcohol
J) The common name of this compound is acetic acid.
K) the type of ester produced when phosphoric acid reacts with one molecule of alcohol
L) the transfer of a phosphoryl group from one molecule to another
M) The common name of this compound is formic acid.

N) B) and D)
O) G) and L)

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Hydrolysis of the ester ethyl acetate produces


A) ethanol and acetic acid.
B) butanol.
C) butanal and ethanol.
D) ethanal and acetic acid.
E) butanoic acid.

F) A) and D)
G) B) and D)

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Which carboxylic acid is used to prepare the ester shown? Which carboxylic acid is used to prepare the ester shown?   A) CH<sub>3</sub>CH<sub>2</sub>COOH B) CH<sub>3</sub>COOH C) (CH<sub>3</sub>) <sub>2</sub>CHCOOH D) (CH<sub>3</sub>) <sub>2</sub>CHCH<sub>2</sub>COOH E) CH<sub>3</sub> (C H<sub>2</sub> <sub> </sub>   COOH


A) CH3CH2COOH
B) CH3COOH
C) (CH3) 2CHCOOH
D) (CH3) 2CHCH2COOH
E) CH3 (C H2

Which carboxylic acid is used to prepare the ester shown?   A) CH<sub>3</sub>CH<sub>2</sub>COOH B) CH<sub>3</sub>COOH C) (CH<sub>3</sub>) <sub>2</sub>CHCOOH D) (CH<sub>3</sub>) <sub>2</sub>CHCH<sub>2</sub>COOH E) CH<sub>3</sub> (C H<sub>2</sub> <sub> </sub>   COOH
COOH

F) A) and D)
G) A) and C)

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Which acid would be expected to have the highest boiling point?


A) acetic
B) benzoic
C) formic
D) oxalic
E) stearic

F) A) and B)
G) B) and E)

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Which of the following has the highest boiling point?


A) ethane,CH3CH3
B) dimethyl ketone,CH3COCH3
C) ethyl alcohol,CH3CH2OH
D) acetic acid,CH3COOH
E) formaldehyde,HCHO

F) A) and B)
G) A) and C)

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