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One step in the metabolism of glucose is depicted below. Which statement best describes how the equilibrium system would respond if the amount of dihydroxyacetone phosphate is decreased? One step in the metabolism of glucose is depicted below. Which statement best describes how the equilibrium system would respond if the amount of dihydroxyacetone phosphate is decreased?   A) The system would shift to the left, consuming more dihydroxyacetone phosphate. B) The system would shift to the right, producing more dihydroxyacetone phosphate and glyceraldehyde 3-phosphate. C) The system would shift to the left, producing more fructose 1, 6-bisphosphate. D) The system would shift to the right, consuming some glyceraldehyde 3-phosphate and producing more dihydroxyacetone phosphate.


A) The system would shift to the left, consuming more dihydroxyacetone phosphate.
B) The system would shift to the right, producing more dihydroxyacetone phosphate and glyceraldehyde 3-phosphate.
C) The system would shift to the left, producing more fructose 1, 6-bisphosphate.
D) The system would shift to the right, consuming some glyceraldehyde 3-phosphate and producing more dihydroxyacetone phosphate.

E) A) and B)
F) A) and C)

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Increasing the temperature of a reaction mixture usually results in a decrease in the reaction rate.

A) True
B) False

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Le Châtelier's principle is a general rule used to explain the effect of a change in reaction conditions on equilibrium.

A) True
B) False

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Which of the following is NOT a reasonable assumption about the chemical reaction whose energy diagram is depicted below?  Which of the following is NOT a reasonable assumption about the chemical reaction whose energy diagram is depicted below?   A) The activation energy for the reaction is 100kJ. B) The reaction is exothermic. C)  \Delta H= -25kJ D) The reaction is favorable.


A) The activation energy for the reaction is 100kJ.
B) The reaction is exothermic.
C) Δ\Delta H= -25kJ
D) The reaction is favorable.

E) None of the above
F) B) and D)

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Which statement concerning the reversible reaction 2 NO2(g) Which statement concerning the reversible reaction 2 NO<sub>2</sub>(g)    N<sub>2</sub>O<sub>4</sub>(g) is true? A) NO<sub>2</sub> is the product of the forward reaction. B) The reverse reaction produces N<sub>2</sub>O<sub>4</sub>. C) At the start of the reaction, the forward and reverse reaction rates are equal. D) As the forward reaction progresses and more N<sub>2</sub>O<sub>4</sub> is formed, the reverse reaction rate increases. N2O4(g) is true?


A) NO2 is the product of the forward reaction.
B) The reverse reaction produces N2O4.
C) At the start of the reaction, the forward and reverse reaction rates are equal.
D) As the forward reaction progresses and more N2O4 is formed, the reverse reaction rate increases.

E) A) and C)
F) All of the above

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Consider the reaction, C2H4(g) + H2(g) \rightarrow C2H6(g) , where Δ\Delta H = -137 kJ. How many kilojoules are released when 55.3 g of C2H4 reacts?


A) 137 kJ are released
B) 270. kJ are released
C) 1.13 × 103 kJ are released
D) 7.58 × 103 kJ are released

E) All of the above
F) B) and D)

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Consider the reaction: N2(g) + O2(g) Consider the reaction: N<sub>2</sub>(g) + O<sub>2</sub>(g)    2 NO(g) . If [N<sub>2</sub>] = 0.520 M, [O<sub>2</sub>] = 0.0662 M, and [NO] = 0.00956 at equilibrium, what is the value of K? A) 3.60 B) 0.278 C) 377 D) 0.00265 2 NO(g) . If [N2] = 0.520 M, [O2] = 0.0662 M, and [NO] = 0.00956 at equilibrium, what is the value of K?


A) 3.60
B) 0.278
C) 377
D) 0.00265

E) B) and D)
F) A) and B)

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Kinetic energy is the energy associated with movement; potential energy is the energy inherent in an object due to its position or composition.

A) True
B) False

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Once equilibrium is reached in a chemical reaction, reactants stop forming products.

A) True
B) False

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Consider the reaction: PCl3(g) + Cl2(g) Consider the reaction: PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)    PCl<sub>5</sub>(g) . If [PCl<sub>3</sub>] = 0.78 M, [Cl<sub>2</sub>] = 0.44 M, and [PCl<sub>5</sub>] = 0.88 at equilibrium, what is the value of K? A) 0.39 B) 1.4 C) 2.6 D) 0.72 PCl5(g) . If [PCl3] = 0.78 M, [Cl2] = 0.44 M, and [PCl5] = 0.88 at equilibrium, what is the value of K?


A) 0.39
B) 1.4
C) 2.6
D) 0.72

E) A) and C)
F) B) and C)

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An equilibrium constant with a value of 8.0 × 106 indicates that at equilibrium


A) the reactants are favored.
B) the products are favored.
C) approximately equal concentrations of reactants and products are present.
D) there are more reactants present than products.

E) B) and D)
F) A) and D)

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Exothermic reactions involve the formation of products having lower energy than the reactants.

A) True
B) False

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Bond dissociation energies are always positive numbers.

A) True
B) False

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A reversible reaction in which K = 9.65 × 10-14 contains a negligible amount of reactants at equilibrium.

A) True
B) False

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When heat is added to an exothermic equilibrium reaction, the reaction shifts to form more ____.

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Walking at a brisk pace burns off about 280 Cal/h. How long would you have to walk to burn off the Calories obtained from eating a candy bar that contained 3 g of protein, 12 g of fat, and 28 g of carbohydrates?


A) 55 minutes
B) 230 minutes
C) 50 minutes
D) 210 minutes

E) C) and D)
F) All of the above

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The Δ\Delta H for the reaction depicted by the energy diagram below is ____.  The \Delta H for the reaction depicted by the energy diagram below is ____.

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In the energy diagram shown below, C labels the _____. In the energy diagram shown below, C labels the _____.

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Which term correctly describes a reaction in which the energy of the products is higher than the energy of the reactants?


A) oxidation-reduction
B) endothermic
C) exothermic
D) combustion

E) A) and B)
F) A) and C)

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The expression for the equilibrium constant, K, for the general reaction: a A + b B The expression for the equilibrium constant, K, for the general reaction: a A + b B   c C + d D is   . c C + d D is The expression for the equilibrium constant, K, for the general reaction: a A + b B   c C + d D is   . .

A) True
B) False

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